Physics · 2.1.3 Gas pressure · Boyle's law · Paper 6
Gas Laws. Squeeze it.
Compress a fixed mass of gas at constant temperature and watch the pressure rise. Verify Boyle's law: pV = constant, so p ∝ 1/V. Switch to the pressure law to see how heating raises pressure at constant volume.
0625 Topic 2.1.3 — Gas pressure
Boyle's law pV = const
Paper 6 — ATP
Variables
40
20
1.0
Live readouts
Pressure p
101 kPa
Volume V
40 cm³
Temperature
293 K
pV (should be constant)
4040
Boyle's law: at constant temperature, p × V = constant for a fixed mass of gas.
Trial data
Record at five volumes (or temperatures) to test the law.
p vs 1/V — straight line ⇒ p ∝ 1/V
📋 Method (Cambridge ATP procedure)
- Trap a fixed mass of dry air in a sealed syringe/glass tube connected to a pressure gauge.
- Boyle's law: keep temperature constant; change the volume slowly (so no heating occurs) and record p for each V.
- Pressure law: keep the volume fixed; warm the gas in a water bath and record p at several temperatures.
- Compress slowly and wait before reading so the gas stays at room temperature.
Analytical control: plot p against 1/V (straight line through origin ⇒ pV = constant); or plot p against T in kelvin (straight line through origin ⇒ p ∝ T).
⚠ Sources of error & precautions
- Compress slowly — fast compression heats the gas, breaking the constant-temperature condition.
- No leaks — the mass of gas must stay fixed; check seals.
- Read the gauge and volume scale perpendicular to avoid parallax.
- For the pressure law, use absolute temperature in kelvin (°C + 273).
🎯 Syllabus reference (0625)
- 2.1.3 Gases & the absolute scale of temperature — describe how a gas exerts pressure through molecular collisions; recall and use pV = constant at constant temperature; relate pressure and temperature for a fixed volume; use the kelvin scale.